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The pH of a solution is defined as the negative logarithm of the concentration of H+, and the pOH is defined as the negative logarithm of the concentration of OH-. For example, the pH of a 0.01M solution of hydrochloric acid (HCl) is equal to 2 (pH = −log 10 (0.01)), while the pOH of a 0.01M solution of sodium hydroxide (NaOH) is equal to 2 ...
The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant, Ka of the acid, and the concentrations of the species in solution. [2] Simulated titration of an acidified solution of a weak acid ( pKa = 4.7) with alkali. To derive the equation a number of ...
e. In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction. known as dissociation in the context of acid–base reactions.
The partition coefficient, abbreviated P, is defined as a particular ratio of the concentrations of a solute between the two solvents (a biphase of liquid phases), specifically for un- ionized solutes, and the logarithm of the ratio is thus log P. [10] : 275ff When one of the solvents is water and the other is a non-polar solvent, then the log ...
The equations, derived from the acidity constant and basicity constant, states that when pH equals the pK a or pK b value of the indicator, both species are present in a 1:1 ratio. If pH is above the p K a or p K b value, the concentration of the conjugate base is greater than the concentration of the acid, and the color associated with the ...
In biochemistry and pharmacology, the Hill equation refers to two closely related equations that reflect the binding of ligands to macromolecules, as a function of the ligand concentration. A ligand is "a substance that forms a complex with a biomolecule to serve a biological purpose" ( ligand definition ), and a macromolecule is a very large ...
In mathematics, the logarithm is the inverse function to exponentiation. That means that the logarithm of a number x to the base b is the exponent to which b must be raised to produce x. For example, since 1000 = 103, the logarithm base of 1000 is 3, or log10 (1000) = 3.
A Bjerrum plot is obtained by using these three equations to plot these three species against pH = −log 10 [H +] eq, for given K 1, K 2 and DIC. The fractions in these equations give the three species' relative proportions, and so if DIC is unknown, or the actual concentrations are unimportant, these proportions may be plotted instead.