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The pH of a solution is defined as the negative logarithm of the concentration of H+, and the pOH is defined as the negative logarithm of the concentration of OH-. For example, the pH of a 0.01M solution of hydrochloric acid (HCl) is equal to 2 (pH = −log 10 (0.01)), while the pOH of a 0.01M solution of sodium hydroxide (NaOH) is equal to 2 ...
The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant, Ka of the acid, and the concentrations of the species in solution. [2] Simulated titration of an acidified solution of a weak acid ( pKa = 4.7) with alkali. To derive the equation a number of ...
The partition coefficient, abbreviated P, is defined as a particular ratio of the concentrations of a solute between the two solvents (a biphase of liquid phases), specifically for un- ionized solutes, and the logarithm of the ratio is thus log P. [10] : 275ff When one of the solvents is water and the other is a non-polar solvent, then the log ...
The logarithm is denoted "log b x" (pronounced as "the logarithm of x to base b", "the base-b logarithm of x", or most commonly "the log, base b, of x "). An equivalent and more succinct definition is that the function log b is the inverse function to the function . Examples
where log(x) is the common logarithm of x, and pK BH + is −log(K) for the dissociation of BH +, which is the conjugate acid of a very weak base B, with a very negative pK BH +. In this way, it is rather as if the pH scale has been extended to very negative values. Hammett originally used a series of anilines with electron-withdrawing groups ...
The Brønsted–Lowry theory (also called proton theory of acids and bases [1]) is an acid–base reaction theory which was first developed by Johannes Nicolaus Brønsted and Thomas Martin Lowry independently in 1923. [2] [3] The basic concept of this theory is that when an acid and a base react with each other, the acid forms its conjugate ...
A pH indicator is a halochromic chemical compound added in small amounts to a solution so the pH ( acidity or basicity) of the solution can be determined visually or spectroscopically by changes in absorption and/or emission properties. [1] Hence, a pH indicator is a chemical detector for hydronium ions (H 3 O +) or hydrogen ions (H +) in the ...
The solution was initially prepared at 20 °C and then stored for 2 days at 4 °C. In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubility of a substance in ...